Hilgardia
Hilgardia
Hilgardia
University of California
Hilgardia

Chromotropic acid method for determining 2,4-D residues in rinses

Authors

Louis C. Erickson
B. L. Brannaman

Authors Affiliations

Louis C. Erickson was Associate Plant Physiologist in the Experiment Station, Riverside; B. L. Brannaman was Principal Laboratory Technician in the Experiment Station, Riverside.

Publication Information

Hilgardia 23(7):175-184. DOI:10.3733/hilg.v23n07p175. December 1954.

PDF of full article, Cite this article

Abstract

The chromotropic acid method for determining small amounts of 2,4-D was placed on a quantitative basis and used to determine the extent of contamination of various metals and glass left in contact with 2,4-D.

Aluminum, iron, and zinc retained the greatest amounts of 2,4-D, while copper, tin, and glass were more readily decontaminated.

Several prolonged rinses of water were effective in removing the salts but not the esters of 2,4-D. The esters required soaking in an organic solvent. The latter procedure would be expensive and hazardous for cleaning spray equipment.

The best way of avoiding injury to sensitive plants would be to have separate spray equipment for 2,4-D.

Literature Cited

Boos R. N. Quantitative colorimetric microdetermination of methanol with chromotropic acid reagent. Analyt. Chem. 1948. 20:964-65. DOI: 10.1021/ac60022a032 [CrossRef]

Boyd M. J., Logan M. A. Colorimetric determination of serine. Jour. Biol. Chem. 1942. 146:279-87.

Bricker C. E., Vail W. A. Microdetermination of formaldehyde with chromotropic acid. Analyt. Chem. 1950. 22:720-22. DOI: 10.1021/ac60041a032 [CrossRef]

Eegriwe E. Reaktionen und Reagenzien zum nachweis organischer Verbindungen. Ztschr. f. Analyt. Chem. 1937. 110:22-25. DOI: 10.1007/BF01392026 [CrossRef]

Freed V. H. Qualitative reaction for 2,4-dichlorophenoxyacetic acid. Science. 1948. 107:98-99. DOI: 10.1126/science.107.2769.98 [CrossRef]

LeTourneau Duane, Krog Norman. The use of chromotropic acid for the quantitative determination of 2,4-dichlorophenoxyacetic acid. Plant Physiol. 1952. 27:822-27. DOI: 10.1104/pp.27.4.822 [CrossRef]

Lucas E. H., Hamner C. L. Inactivation of 2,4-D by adsorption on charcoal. Science. 1947. 105:340 DOI: 10.1126/science.105.2726.340 [CrossRef]

Marquardt R. P., Luce E. N. Determination of small amounts of 2,4-dichlorophenoxyacetic acid in milk. Analyt. Chem. 1951. 23:1484-86. DOI: 10.1021/ac60058a033 [CrossRef]

Snedecor George W. Statistical methods. 1940. 3d ed. Ames, Iowa: Collegiate Press, Inc. chap. 4

Stewart Wm. S., Gammon Cyril, Hield H. Z. Deposit of 2,4-D and kill of wild grapevines by helicopter spray application. Amer. Jour. Bot. 1952. 39:1-5. DOI: 10.2307/2438086 [CrossRef]

Treadwell F. P., Hall W. T. Analytical Chemistry. 1942. 2:9th ed. New York: John Wiley &; Sons. chap. 3 (revised by

Voisenet M. E. Sur une réaction tres sensible de la formaldéhyde et des composés oxygénés de l’azote et qui est aussi une réaction de coloration des matiéres albuminoídes. Soc. Chim. de France Bul. 1905. 33:1198-1214. (Cf. Merck Index, 5th ed., 1940, p. 952)

Welcher Frank J. Organic analytical reagents. 1947. 1: New York: C. Van Nostrand Company, Inc. chap. 12

Erickson L, Brannaman B. 1954. Chromotropic acid method for determining 2,4-D residues in rinses. Hilgardia 23(7):175-184. DOI:10.3733/hilg.v23n07p175
Webmaster Email: sjosterman@ucanr.edu